Poly[[di­aqua­deca-μ(2)-cyanido-κ(20) C:N-hexa­cyanido-κ(6) C-bis­(μ(2)-5-methyl­pyrimidine-κ(2) N:N′)bis­(5-methyl­pyrimidine-κN)tricopper(II)ditungstate(V)] dihydrate]

In the title complex, {[Cu(3)[W(CN)(8)](2)(C(5)H(6)N(2))(4)(H(2)O)(2)]·2H(2)O}(n), the coordination polyhedron of the eight-coordinated W(V) atom is a bicapped trigonal prism, in which five CN groups are bridged to Cu(II) ions, and the other three CN groups are terminally bound. Two of the Cu(II) io...

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Detalles Bibliográficos
Autores principales: Tsunobuchi, Yoshihide, Kaneko, Souhei, Nakabayashi, Koji, Ohkoshi, Shin-ichi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998256/
https://www.ncbi.nlm.nih.gov/pubmed/24764817
http://dx.doi.org/10.1107/S1600536814000166

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998256/
https://www.ncbi.nlm.nih.gov/pubmed/24764817
http://dx.doi.org/10.1107/S1600536814000166

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