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Poly[[diaquadeca-μ(2)-cyanido-κ(20) C:N-hexacyanido-κ(6) C-bis(μ(2)-5-methylpyrimidine-κ(2) N:N′)bis(5-methylpyrimidine-κN)tricopper(II)ditungstate(V)] dihydrate]
In the title complex, {[Cu(3)[W(CN)(8)](2)(C(5)H(6)N(2))(4)(H(2)O)(2)]·2H(2)O}(n), the coordination polyhedron of the eight-coordinated W(V) atom is a bicapped trigonal prism, in which five CN groups are bridged to Cu(II) ions, and the other three CN groups are terminally bound. Two of the Cu(II) io...
Autores principales: | Tsunobuchi, Yoshihide, Kaneko, Souhei, Nakabayashi, Koji, Ohkoshi, Shin-ichi |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998256/ https://www.ncbi.nlm.nih.gov/pubmed/24764817 http://dx.doi.org/10.1107/S1600536814000166 |
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