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Hydrido(prolinato-κ(2) N,O)tris­(tri­methyl­phosphane-κP)iridium(III) hexa­fluorido­phosphate

The title complex, [Ir(C(5)H(8)NO(2))H(C(3)H(9)P)(3)]PF(6), has two independent anion–cation pairs in the asymmetric unit. The geometry about each Ir(III) atom is pseudo-octa­hedral with a meridional arrangement of the P(CH(3))(3) ligands, N,O-bidentate coordination of prolinate and a hydride ligand...

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Detalles Bibliográficos
Autores principales: Merola, Joseph S., Roy, Christopher P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998271/
https://www.ncbi.nlm.nih.gov/pubmed/24764832
http://dx.doi.org/10.1107/S1600536814001834