Dimethyl 5-acetyl-1-hy­droxy-4-methyl-1H-pyrrole-2,3-di­carboxyl­ate, an oxidation-resistant N-hy­droxy­pyrrole

The title compound, C(11)H(13)NO(6), exhibits an intra­molecular O–H⋯O=C hydrogen bond between the N-hydroxyl H atom and carbonyl O atom of the neighboring acetyl group. This finding contradicts a previously published model in which the hydrogen bond was postulated to occur with the neighboring carb...

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Detalles Bibliográficos
Autores principales: Rosen, Gerald M., Muralidharan, Sukumaran, Zavalij, Peter Y., Kao, Joseph P. Y.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998280/
https://www.ncbi.nlm.nih.gov/pubmed/24764841
http://dx.doi.org/10.1107/S1600536813034466

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998280/
https://www.ncbi.nlm.nih.gov/pubmed/24764841
http://dx.doi.org/10.1107/S1600536813034466

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