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μ-Oxido-bis[hydridotris(trimethylphosphane-κP)iridium(III)](Ir—Ir) bis(tetrafluoridoborate) dihydrate
The title compound, [Ir(2)H(2)O(C(3)H(9)P)(6)](BF(4))(2)·2H(2)O, was isolated from the reaction between [Ir(COD)(PMe(3))(3)]BF(4) and H(2) in water (COD is cycloocta-1,5-diene). The asymmetric unit consists of one Ir(III) atom bonded to three PMe(3) groups, one hydride ligand and half an oxide liga...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998581/ https://www.ncbi.nlm.nih.gov/pubmed/24826089 http://dx.doi.org/10.1107/S160053681400453X |