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Generating and Stabilizing Co(I) in a Nanocage Environment
[Image: see text] A discrete nanocage of core–shell design, in which carboxylic acid groups were tethered to the core and silanol to the shell interior, was found to react with Co(2)(CO)(8) to form and stabilize a Co(I)–CO species. The singular CO stretching band of this new Co species at 1958 cm(–1...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4004243/ https://www.ncbi.nlm.nih.gov/pubmed/24673361 http://dx.doi.org/10.1021/ja412446y |