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Analyzing Site Selectivity in Rh(2)(esp)(2)-Catalyzed Intermolecular C–H Amination Reactions

[Image: see text] Predicting site selectivity in C–H bond oxidation reactions involving heteroatom transfer is challenged by the small energetic differences between disparate bond types and the subtle interplay of steric and electronic effects that influence reactivity. Herein, the factors governing...

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Detalles Bibliográficos
Autores principales: Bess, Elizabeth N., DeLuca, Ryan J., Tindall, Daniel J., Oderinde, Martins S., Roizen, Jennifer L., Du Bois, J., Sigman, Matthew S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4004253/
https://www.ncbi.nlm.nih.gov/pubmed/24673332
http://dx.doi.org/10.1021/ja5015508