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Hydrogen Tunneling in a Prokaryotic Lipoxygenase
[Image: see text] A bacterial lipoxygenase (LOX) shows a deuterium kinetic isotope effect (KIE) that is similar in magnitude and temperature dependence to the very large KIE of eukaryotic LOXs. This occurs despite the evolutionary distance, an ∼25% smaller catalytic domain, and an increase in E(a) o...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4004258/ https://www.ncbi.nlm.nih.gov/pubmed/24641705 http://dx.doi.org/10.1021/bi500070q |