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Spontaneous transfer of chirality in an atropisomerically enriched two-axis system
Perhaps the most well-recognized stereogenic elements within chiral molecules are sp(3)-hybridized carbon atoms possessing four different substituents. However, axes of chirality may also exist about bonds with hindered barriers of rotation, leading to stereoisomers known as atropisomers.(1) Underst...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
2014
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4008667/ https://www.ncbi.nlm.nih.gov/pubmed/24747399 http://dx.doi.org/10.1038/nature13189 |