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Single molecule fluorescence probes dynamics of barrier crossing

Kramers developed the theory on how chemical reaction rates are influenced by the viscosity of the medium(1,2). At the viscosity of water, the kinetics of unimolecular reactions are described by diffusion of a Brownian particle over a free-energy barrier separating reactants and products. For reacti...

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Detalles Bibliográficos
Autores principales: Chung, Hoi Sung, Eaton, William A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4009947/
https://www.ncbi.nlm.nih.gov/pubmed/24153185
http://dx.doi.org/10.1038/nature12649