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LFER Studies Evaluating Solvent Effects on an α-Chloro-and two β,β,β-Trichloro-Ethyl Chloroformate Esters

To provide insight and to identify the occurrence of mechanistic changes in relation to variance in solvent-type, the solvent effects on the rates of solvolysis of three substrates, 2,2,2-trichloro-1,1-dimethylethyl chloroformate, 2,2,2-trichloroethyl chloroformate, and 1-chloroethyl chloroformate,...

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Detalles Bibliográficos
Autores principales: D’Souza, Malcolm J., Sandosky, Brandon, Fernandez-Bueno, Gabriel A., McAneny, Matthew J., Kevill, Dennis N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011389/
https://www.ncbi.nlm.nih.gov/pubmed/24812595
http://dx.doi.org/10.13179/canchemtrans.2014.02.02.0093