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Carboxylate-Assisted C(sp(3))–H Activation in Olefin Metathesis-Relevant Ruthenium Complexes

[Image: see text] The mechanism of C–H activation at metathesis-relevant ruthenium(II) benzylidene complexes was studied both experimentally and computationally. Synthesis of a ruthenium dicarboxylate at a low temperature allowed for direct observation of the C–H activation step, independent of the...

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Detalles Bibliográficos
Autores principales: Cannon, Jeffrey S., Zou, Lufeng, Liu, Peng, Lan, Yu, O’Leary, Daniel J., Houk, K. N., Grubbs, Robert H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4017616/
https://www.ncbi.nlm.nih.gov/pubmed/24731019
http://dx.doi.org/10.1021/ja5021958