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Carboxylate-Assisted C(sp(3))–H Activation in Olefin Metathesis-Relevant Ruthenium Complexes
[Image: see text] The mechanism of C–H activation at metathesis-relevant ruthenium(II) benzylidene complexes was studied both experimentally and computationally. Synthesis of a ruthenium dicarboxylate at a low temperature allowed for direct observation of the C–H activation step, independent of the...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4017616/ https://www.ncbi.nlm.nih.gov/pubmed/24731019 http://dx.doi.org/10.1021/ja5021958 |