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A Catalytic Enantiotopic-Group-Selective Suzuki Reaction for the Construction of Chiral Organoboronates

[Image: see text] Catalytic enantiotopic-group-selective cross-couplings of achiral geminal bis(pinacolboronates) provide a route for the construction of nonracemic chiral organoboronates. In the presence of a chiral monodentate taddol-derived phosphoramidite ligand, these reactions occur with high...

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Detalles Bibliográficos
Autores principales: Sun, Chunrui, Potter, Bowman, Morken, James P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4021567/
https://www.ncbi.nlm.nih.gov/pubmed/24564423
http://dx.doi.org/10.1021/ja500029w