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Tri-μ-chlorido-bis[(η(5)-pentamethylcyclopentadienyl)rhodium(III)] hexafluoridophosphate from synchrotron radiation
In the title complex salt, [{(η(5)-C(5)Me(5))Rh}(2)(μ-Cl)(3)]PF(6), the dinuclear, single-charged cation is formed by the cojoining of two classic (η(5)-C(5)Me(5))RhCl(3) ‘piano-stool’ units by bridging of the three choride ligand ‘legs’. The crystal structure shows several close H⋯F contacts betwee...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4029212/ https://www.ncbi.nlm.nih.gov/pubmed/24855466 http://dx.doi.org/10.1107/S1600536813032480 |