Tri-μ-chlorido-bis­[(η(5)-penta­methyl­cyclo­penta­dien­yl)rhodium(III)] hexa­fluorido­phosphate from synchrotron radiation

In the title complex salt, [{(η(5)-C(5)Me(5))Rh}(2)(μ-Cl)(3)]PF(6), the dinuclear, single-charged cation is formed by the cojoining of two classic (η(5)-C(5)Me(5))RhCl(3) ‘piano-stool’ units by bridging of the three choride ligand ‘legs’. The crystal structure shows several close H⋯F contacts betwee...

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Detalles Bibliográficos
Autores principales: Ezzedinloo, Lida, Shrestha, Sumi, Bhadbhade, Mohan, Colbran, Stephen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4029212/
https://www.ncbi.nlm.nih.gov/pubmed/24855466
http://dx.doi.org/10.1107/S1600536813032480
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author Ezzedinloo, Lida
Shrestha, Sumi
Bhadbhade, Mohan
Colbran, Stephen
author_facet Ezzedinloo, Lida
Shrestha, Sumi
Bhadbhade, Mohan
Colbran, Stephen
author_sort Ezzedinloo, Lida
collection PubMed
description In the title complex salt, [{(η(5)-C(5)Me(5))Rh}(2)(μ-Cl)(3)]PF(6), the dinuclear, single-charged cation is formed by the cojoining of two classic (η(5)-C(5)Me(5))RhCl(3) ‘piano-stool’ units by bridging of the three choride ligand ‘legs’. The crystal structure shows several close H⋯F contacts between the hexa­fluorido­phosphate counter-ions and the C(5)Me(5) ligands.
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spelling pubmed-40292122014-05-22 Tri-μ-chlorido-bis­[(η(5)-penta­methyl­cyclo­penta­dien­yl)rhodium(III)] hexa­fluorido­phosphate from synchrotron radiation Ezzedinloo, Lida Shrestha, Sumi Bhadbhade, Mohan Colbran, Stephen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex salt, [{(η(5)-C(5)Me(5))Rh}(2)(μ-Cl)(3)]PF(6), the dinuclear, single-charged cation is formed by the cojoining of two classic (η(5)-C(5)Me(5))RhCl(3) ‘piano-stool’ units by bridging of the three choride ligand ‘legs’. The crystal structure shows several close H⋯F contacts between the hexa­fluorido­phosphate counter-ions and the C(5)Me(5) ligands. International Union of Crystallography 2013-12-11 /pmc/articles/PMC4029212/ /pubmed/24855466 http://dx.doi.org/10.1107/S1600536813032480 Text en © Ezzedinloo et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ezzedinloo, Lida
Shrestha, Sumi
Bhadbhade, Mohan
Colbran, Stephen
Tri-μ-chlorido-bis­[(η(5)-penta­methyl­cyclo­penta­dien­yl)rhodium(III)] hexa­fluorido­phosphate from synchrotron radiation
title Tri-μ-chlorido-bis­[(η(5)-penta­methyl­cyclo­penta­dien­yl)rhodium(III)] hexa­fluorido­phosphate from synchrotron radiation
title_full Tri-μ-chlorido-bis­[(η(5)-penta­methyl­cyclo­penta­dien­yl)rhodium(III)] hexa­fluorido­phosphate from synchrotron radiation
title_fullStr Tri-μ-chlorido-bis­[(η(5)-penta­methyl­cyclo­penta­dien­yl)rhodium(III)] hexa­fluorido­phosphate from synchrotron radiation
title_full_unstemmed Tri-μ-chlorido-bis­[(η(5)-penta­methyl­cyclo­penta­dien­yl)rhodium(III)] hexa­fluorido­phosphate from synchrotron radiation
title_short Tri-μ-chlorido-bis­[(η(5)-penta­methyl­cyclo­penta­dien­yl)rhodium(III)] hexa­fluorido­phosphate from synchrotron radiation
title_sort tri-μ-chlorido-bis­[(η(5)-penta­methyl­cyclo­penta­dien­yl)rhodium(iii)] hexa­fluorido­phosphate from synchrotron radiation
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4029212/
https://www.ncbi.nlm.nih.gov/pubmed/24855466
http://dx.doi.org/10.1107/S1600536813032480
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AT bhadbhademohan trimchloridobisē5pentamethylcyclopentadienylrhodiumiiihexafluoridophosphatefromsynchrotronradiation
AT colbranstephen trimchloridobisē5pentamethylcyclopentadienylrhodiumiiihexafluoridophosphatefromsynchrotronradiation

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