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Tri-μ-chlorido-bis[(η(5)-pentamethylcyclopentadienyl)rhodium(III)] hexafluoridophosphate from synchrotron radiation

In the title complex salt, [{(η(5)-C(5)Me(5))Rh}(2)(μ-Cl)(3)]PF(6), the dinuclear, single-charged cation is formed by the cojoining of two classic (η(5)-C(5)Me(5))RhCl(3) ‘piano-stool’ units by bridging of the three choride ligand ‘legs’. The crystal structure shows several close H⋯F contacts betwee...

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Detalles Bibliográficos
Autores principales:	Ezzedinloo, Lida, Shrestha, Sumi, Bhadbhade, Mohan, Colbran, Stephen
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	International Union of Crystallography 2013
Materias:	Metal-Organic Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4029212/ https://www.ncbi.nlm.nih.gov/pubmed/24855466 http://dx.doi.org/10.1107/S1600536813032480

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