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Boron Carboxylate Catalysis of Homoallylboration

[Image: see text] Boron tris(trifluoroacetate) is identified as the first effective catalyst for the homoallyl- and homocrotylboration of aldehydes by cyclopropylcarbinylboronates. NMR spectroscopic studies and theoretical calculations of key intermediates and transition states both suggest that a l...

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Detalles Bibliográficos
Autores principales: Dugas, Gabrielle J., Lam, Yu-hong, Houk, K. N., Krauss, Isaac J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4033657/
https://www.ncbi.nlm.nih.gov/pubmed/24754566
http://dx.doi.org/10.1021/jo500599h