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Photofragmentation of Gas-Phase Lanthanide Cyclopentadienyl Complexes: Experimental and Time-Dependent Excited-State Molecular Dynamics

[Image: see text] Unimolecular gas-phase laser-photodissociation reaction mechanisms of open-shell lanthanide cyclopentadienyl complexes, Ln(Cp)(3) and Ln(TMCp)(3), are analyzed from experimental and computational perspectives. The most probable pathways for the photoreactions are inferred from phot...

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Detalles Bibliográficos
Autores principales: Chen, Jiangchao, Hochstatter, Andrew M., Kilin, Dmitri, May, P. Stanley, Meng, Qingguo, Berry, Mary T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4045319/
https://www.ncbi.nlm.nih.gov/pubmed/24910492
http://dx.doi.org/10.1021/om400953q