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Photoinitiated Oxidative Addition of CF(3)I to Gold(I) and Facile Aryl-CF(3) Reductive Elimination
[Image: see text] Herein we report the mechanism of oxidative addition of CF(3)I to Au(I), and remarkably fast C(aryl)–CF(3) bond reductive elimination from Au(III) cations. CF(3)I undergoes a fast, formal oxidative addition to R(3)PAuR′ (R = Cy, R′ = 3,5-F(2)-C(6)H(4), 4-F-C(6)H(4), C(6)H(5), 4-Me-...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4046758/ https://www.ncbi.nlm.nih.gov/pubmed/24836526 http://dx.doi.org/10.1021/ja503974x |