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Photoinitiated Oxidative Addition of CF(3)I to Gold(I) and Facile Aryl-CF(3) Reductive Elimination

[Image: see text] Herein we report the mechanism of oxidative addition of CF(3)I to Au(I), and remarkably fast C(aryl)–CF(3) bond reductive elimination from Au(III) cations. CF(3)I undergoes a fast, formal oxidative addition to R(3)PAuR′ (R = Cy, R′ = 3,5-F(2)-C(6)H(4), 4-F-C(6)H(4), C(6)H(5), 4-Me-...

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Detalles Bibliográficos
Autores principales:	Winston, Matthew S., Wolf, William J., Toste, F. Dean
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2014
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4046758/ https://www.ncbi.nlm.nih.gov/pubmed/24836526 http://dx.doi.org/10.1021/ja503974x

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