Propargyltrimethylsilanes as Allene Equivalents in Transition Metal-Catalyzed [5 + 2] Cycloadditions

[Image: see text] Conventional allenes have not been effective π-reactive 2-carbon components in many intermolecular cycloadditions including metal-catalyzed [5 + 2] cycloadditions. We report herein that rhodium-catalyzed [5 + 2] cycloadditions of propargyltrimethylsilanes and vinylcyclopropanes pro...

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Detalles Bibliográficos
Autores principales: Wender, Paul A., Inagaki, Fuyuhiko, Pfaffenbach, Magnus, Stevens, Matthew C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051429/
https://www.ncbi.nlm.nih.gov/pubmed/24819093
http://dx.doi.org/10.1021/ol501114q

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051429/
https://www.ncbi.nlm.nih.gov/pubmed/24819093
http://dx.doi.org/10.1021/ol501114q

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