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General Route for Preparing β-Nitrocarbonyl Compounds Using Copper Thermal Redox Catalysis
[Image: see text] Using a simple copper catalyst, the alkylation of nitroalkanes with α-bromocarbonyls is now possible. This method provides a general, functional group tolerant route to β-nitrocarbonyl compounds, including nitro amides, esters, ketones, and aldehydes. The highly sterically dense, f...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American
Chemical Society
2014
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051431/ https://www.ncbi.nlm.nih.gov/pubmed/24870052 http://dx.doi.org/10.1021/ol5014153 |