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General Route for Preparing β-Nitrocarbonyl Compounds Using Copper Thermal Redox Catalysis

[Image: see text] Using a simple copper catalyst, the alkylation of nitroalkanes with α-bromocarbonyls is now possible. This method provides a general, functional group tolerant route to β-nitrocarbonyl compounds, including nitro amides, esters, ketones, and aldehydes. The highly sterically dense, f...

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Detalles Bibliográficos
Autores principales: Gietter, Amber A. S., Gildner, Peter G., Cinderella, Andrew P., Watson, Donald A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051431/
https://www.ncbi.nlm.nih.gov/pubmed/24870052
http://dx.doi.org/10.1021/ol5014153