Tuning of the Copper–Thioether Bond in Tetradentate N(3)S((thioether)) Ligands; O–O Bond Reductive Cleavage via a [Cu(II)(2)(μ-1,2-peroxo)](2+)/[Cu(III)(2)(μ-oxo)(2)](2+) Equilibrium

[Image: see text] Current interest in copper/dioxygen reactivity includes the influence of thioether sulfur ligation, as it concerns the formation, structures, and properties of derived copper-dioxygen complexes. Here, we report on the chemistry of {L-Cu(I)}(2)-(O(2)) species L = (DMM)ESE, (DMM)ESP,...

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Detalles Bibliográficos
Autores principales: Kim, Sunghee, Ginsbach, Jake W., Billah, A. Imtiaz, Siegler, Maxime A., Moore, Cathy D., Solomon, Edward I., Karlin, Kenneth D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4063178/
https://www.ncbi.nlm.nih.gov/pubmed/24854766
http://dx.doi.org/10.1021/ja502974c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4063178/
https://www.ncbi.nlm.nih.gov/pubmed/24854766
http://dx.doi.org/10.1021/ja502974c

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