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Tuning of the Copper–Thioether Bond in Tetradentate N(3)S((thioether)) Ligands; O–O Bond Reductive Cleavage via a [Cu(II)(2)(μ-1,2-peroxo)](2+)/[Cu(III)(2)(μ-oxo)(2)](2+) Equilibrium
[Image: see text] Current interest in copper/dioxygen reactivity includes the influence of thioether sulfur ligation, as it concerns the formation, structures, and properties of derived copper-dioxygen complexes. Here, we report on the chemistry of {L-Cu(I)}(2)-(O(2)) species L = (DMM)ESE, (DMM)ESP,...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4063178/ https://www.ncbi.nlm.nih.gov/pubmed/24854766 http://dx.doi.org/10.1021/ja502974c |