Pendant Ancillary Ligand Switches Off Auto-Oxidation of Group 13 Metal Alkyl Compounds Bearing Non-Bulky Alkyl Groups

The reaction of 3,5-di-2-pyridyl-1,2,4-triazole with excess Al(CH(3))(3) and Ga(CH(3))(3) afforded (3,5-di-2-pyridyl-1,2,4-triazolate)Al(CH(3))(2)•3Al(CH(3))(3) (1) and (3,5-di-2-pyridyl-1,2,4-triazolate) Ga(CH(3))(2)•3Ga(CH(3))(3) (2) respectively. 1 and 2 reacted with oxygen gas to produce (CH(3))...

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Detalles Bibliográficos
Autor principal: Kobrsi, Issam
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Public Library of Science 2014
Materias:
Research Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4063902/
https://www.ncbi.nlm.nih.gov/pubmed/24945752
http://dx.doi.org/10.1371/journal.pone.0100626

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4063902/
https://www.ncbi.nlm.nih.gov/pubmed/24945752
http://dx.doi.org/10.1371/journal.pone.0100626

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