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Pendant Ancillary Ligand Switches Off Auto-Oxidation of Group 13 Metal Alkyl Compounds Bearing Non-Bulky Alkyl Groups
The reaction of 3,5-di-2-pyridyl-1,2,4-triazole with excess Al(CH(3))(3) and Ga(CH(3))(3) afforded (3,5-di-2-pyridyl-1,2,4-triazolate)Al(CH(3))(2)•3Al(CH(3))(3) (1) and (3,5-di-2-pyridyl-1,2,4-triazolate) Ga(CH(3))(2)•3Ga(CH(3))(3) (2) respectively. 1 and 2 reacted with oxygen gas to produce (CH(3))...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Public Library of Science
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4063902/ https://www.ncbi.nlm.nih.gov/pubmed/24945752 http://dx.doi.org/10.1371/journal.pone.0100626 |