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Mn K-Edge X-ray Absorption Studies of Oxo- and Hydroxo-manganese(IV) Complexes: Experimental and Theoretical Insights into Pre-Edge Properties
[Image: see text] Mn K-edge X-ray absorption spectroscopy (XAS) was used to gain insights into the geometric and electronic structures of [Mn(II)(Cl)(2)(Me(2)EBC)], [Mn(IV)(OH)(2)(Me(2)EBC)](2+), and [Mn(IV)(O)(OH)(Me(2)EBC)](+), which are all supported by the tetradentate, macrocyclic Me(2)EBC liga...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4066903/ https://www.ncbi.nlm.nih.gov/pubmed/24901026 http://dx.doi.org/10.1021/ic5006902 |