A Mechanochemical Switch to Control Radical Intermediates

[Image: see text] B(12)-dependent enzymes employ radical species with exceptional prowess to catalyze some of the most chemically challenging, thermodynamically unfavorable reactions. However, dealing with highly reactive intermediates is an extremely demanding task, requiring sophisticated control...

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Detalles Bibliográficos
Autores principales: Brunk, Elizabeth, Kellett, Whitney F., Richards, Nigel G. J., Rothlisberger, Ursula
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4067147/
https://www.ncbi.nlm.nih.gov/pubmed/24846280
http://dx.doi.org/10.1021/bi500050k

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4067147/
https://www.ncbi.nlm.nih.gov/pubmed/24846280
http://dx.doi.org/10.1021/bi500050k

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