Cargando…
A Mechanochemical Switch to Control Radical Intermediates
[Image: see text] B(12)-dependent enzymes employ radical species with exceptional prowess to catalyze some of the most chemically challenging, thermodynamically unfavorable reactions. However, dealing with highly reactive intermediates is an extremely demanding task, requiring sophisticated control...
Autores principales: | Brunk, Elizabeth, Kellett, Whitney F., Richards, Nigel G. J., Rothlisberger, Ursula |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American
Chemical Society
2014
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4067147/ https://www.ncbi.nlm.nih.gov/pubmed/24846280 http://dx.doi.org/10.1021/bi500050k |
Ejemplares similares
-
Assigning
the EPR Fine Structure Parameters of the
Mn(II) Centers in Bacillus subtilis Oxalate Decarboxylase by Site-Directed Mutagenesis and DFT/MM Calculations
por: Campomanes, Pablo, et al.
Publicado: (2014) -
Mechanochemical Nucleophilic Substitution of Alcohols via Isouronium Intermediates
por: Dalidovich, Tatsiana, et al.
Publicado: (2022) -
Naphthopyran molecular switches and their emergent mechanochemical reactivity
por: McFadden, Molly E., et al.
Publicado: (2023) -
Methyl Scanning for Mechanochemical Chalcogen‐Bonding Cascade Switches
por: Zhang, Xiang, et al.
Publicado: (2019) -
Mechanoluminescent Materials Enable Mechanochemically Controlled Atom Transfer Radical Polymerization and Polymer Mechanotransduction
por: Li, Zexuan, et al.
Publicado: (2023)