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Rhodium-Catalyzed B–H Activation of 1,2-Azaborines: Synthesis and Characterization of BN Isosteres of Stilbenes

[Image: see text] The first example of catalytic B–H activation of azaborines leading to a new family of stilbene derivatives through dehydrogenative borylation is reported. Ten 1,2-azaborine-based BN isosteres of stilbenes have been synthesized using this method, including a BN isostere of a biolog...

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Detalles Bibliográficos
Autores principales: Brown, Alec N., Zakharov, Lev N., Mikulas, Tanya, Dixon, David A., Liu, Shih-Yuan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4068778/
https://www.ncbi.nlm.nih.gov/pubmed/24916200
http://dx.doi.org/10.1021/ol501362w