Platinum-Catalyzed Reduction of DMF by 1,1,3,3-Tetramethyldisiloxane, HMeSi(2)OSiMe(2)H: New Intermediates HSiMe(2)OSiMe(2)OCH(2)NMe(2) and HSiMe(2)(OSiMe(2))(3)OCH(2)NMe(2) and Their Further Chemical Reactivity

[Image: see text] The use of Karstedt’s catalyst to study the reduction of Me(2)NCHO (DMF) by the popular “dual SiH”-containing tetramethyldisiloxane, HMe(2)SiOSiMe(2)H (1), has revealed that the first step in the process involves an initial single hydrosilylation to form HSiMe(2)OSiMe(2)OCH(2)NMe(2...

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Detalles Bibliográficos
Autores principales: Martinez, Jorge L., Sharma, Hemant K., Arias-Ugarte, Renzo, Pannell, Keith H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4075991/
https://www.ncbi.nlm.nih.gov/pubmed/25013245
http://dx.doi.org/10.1021/om500439p

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4075991/
https://www.ncbi.nlm.nih.gov/pubmed/25013245
http://dx.doi.org/10.1021/om500439p

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