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Platinum-Catalyzed Reduction of DMF by 1,1,3,3-Tetramethyldisiloxane, HMeSi(2)OSiMe(2)H: New Intermediates HSiMe(2)OSiMe(2)OCH(2)NMe(2) and HSiMe(2)(OSiMe(2))(3)OCH(2)NMe(2) and Their Further Chemical Reactivity
[Image: see text] The use of Karstedt’s catalyst to study the reduction of Me(2)NCHO (DMF) by the popular “dual SiH”-containing tetramethyldisiloxane, HMe(2)SiOSiMe(2)H (1), has revealed that the first step in the process involves an initial single hydrosilylation to form HSiMe(2)OSiMe(2)OCH(2)NMe(2...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4075991/ https://www.ncbi.nlm.nih.gov/pubmed/25013245 http://dx.doi.org/10.1021/om500439p |