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Volcano plots in hydrogen electrocatalysis – uses and abuses

Sabatier’s principle suggests, that for hydrogen evolution a plot of the rate constant versus the hydrogen adsorption energy should result in a volcano, and several such plots have been presented in the literature. A thorough examination of the data shows, that there is no volcano once the oxide-cov...

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Detalles Bibliográficos
Autores principales: Quaino, Paola, Juarez, Fernanda, Santos, Elizabeth, Schmickler, Wolfgang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4077405/
https://www.ncbi.nlm.nih.gov/pubmed/24991521
http://dx.doi.org/10.3762/bjnano.5.96