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Theoretical studies on the intramolecular cyclization of 2,4,6-t-Bu(3)C(6)H(2)P=C: and effects of conjugation between the P=C and aromatic moieties
The intramolecular C–H insertion of the Mes*-substituted phosphanylidenecarbene [Mes*P=C:] (Mes* = 2,4,6-t-Bu(3)C(6)H(2)) and physicochemical properties of the cyclized product, 6,8-di-tert-butyl-3,4-dihydro-4,4-dimethyl-1-phosphanaphthalene were studied based on ab initio calculations. Whereas the...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Beilstein-Institut
2014
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4077427/ https://www.ncbi.nlm.nih.gov/pubmed/24991254 http://dx.doi.org/10.3762/bjoc.10.103 |