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Theoretical studies on the intramolecular cyclization of 2,4,6-t-Bu(3)C(6)H(2)P=C: and effects of conjugation between the P=C and aromatic moieties

The intramolecular C–H insertion of the Mes*-substituted phosphanylidenecarbene [Mes*P=C:] (Mes* = 2,4,6-t-Bu(3)C(6)H(2)) and physicochemical properties of the cyclized product, 6,8-di-tert-butyl-3,4-dihydro-4,4-dimethyl-1-phosphanaphthalene were studied based on ab initio calculations. Whereas the...

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Detalles Bibliográficos
Autores principales:	Yoshifuji, Masaaki, Ito, Shigekazu
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Beilstein-Institut 2014
Materias:	Full Research Paper
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4077427/ https://www.ncbi.nlm.nih.gov/pubmed/24991254 http://dx.doi.org/10.3762/bjoc.10.103

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