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Cyclization–endoperoxidation cascade reactions of dienes mediated by a pyrylium photoredox catalyst

Triarylpyrylium salts were employed as single electron photooxidants to catalyze a cyclization–endoperoxidation cascade of dienes. The transformation is presumed to proceed via the intermediacy of diene cation radicals. The nature of the diene component was investigated in this context to determine...

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Detalles Bibliográficos
Autores principales: Gesmundo, Nathan J, Nicewicz, David A
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4077508/
https://www.ncbi.nlm.nih.gov/pubmed/24991279
http://dx.doi.org/10.3762/bjoc.10.128