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Facile scission of isonitrile carbon–nitrogen triple bond using a diborane(4) reagent
Transition metal reagents and catalysts are generally effective to cleave all three bonds (one σ and two π) in a triple bond despite its high bonding energy. Recently, chemistry of single-bond cleavage by using main-group element compounds is rapidly being developed in the absence of transition meta...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Nature Pub. Group
2014
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4083417/ https://www.ncbi.nlm.nih.gov/pubmed/24967910 http://dx.doi.org/10.1038/ncomms5245 |