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Efficient Generation and Increased Reactivity in Cationic Gold via Brønsted Acid or Lewis Acid Assisted Activation of an Imidogold Precatalyst

[Image: see text] Brønsted or Lewis acid assisted activation of an imidogold precatalyst (L-Au-Pht, Pht = phthalimide) offers a superior way to generate cationic gold compared with the commonly used silver-based system. It is also broadly applicable for most common gold-catalyzed reactions. For reac...

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Detalles Bibliográficos
Autores principales: Han, Junbin, Shimizu, Naoto, Lu, Zhichao, Amii, Hideki, Hammond, Gerald B., Xu, Bo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4084832/
https://www.ncbi.nlm.nih.gov/pubmed/24956218
http://dx.doi.org/10.1021/ol501443m