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Factors Controlling the Spectroscopic Properties and Supramolecular Chemistry of an Electron Deficient 5,5-Dimethylphlorin Architecture

[Image: see text] A new 5,5-dimethylphlorin derivative (3H(Phl(CF(3)))) was prepared and studied through a combination of redox, photophysical, and computational experiments. The phlorin macrocycle is significantly distorted from planarity compared to more traditional tetrapyrrole architectures and...

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Detalles Bibliográficos
Autores principales: Pistner, Allen J., Lutterman, Daniel A., Ghidiu, Michael J., Walker, Eric, Yap, Glenn P. A., Rosenthal, Joel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4084833/
https://www.ncbi.nlm.nih.gov/pubmed/25018789
http://dx.doi.org/10.1021/jp5016824