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Factors Controlling the Spectroscopic Properties and Supramolecular Chemistry of an Electron Deficient 5,5-Dimethylphlorin Architecture
[Image: see text] A new 5,5-dimethylphlorin derivative (3H(Phl(CF(3)))) was prepared and studied through a combination of redox, photophysical, and computational experiments. The phlorin macrocycle is significantly distorted from planarity compared to more traditional tetrapyrrole architectures and...
Autores principales: | Pistner, Allen J., Lutterman, Daniel A., Ghidiu, Michael J., Walker, Eric, Yap, Glenn P. A., Rosenthal, Joel |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2014
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4084833/ https://www.ncbi.nlm.nih.gov/pubmed/25018789 http://dx.doi.org/10.1021/jp5016824 |
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