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The Role of Chloride in the Mechanism of O(2) Activation at the Mononuclear Nonheme Fe(II) Center of the Halogenase HctB
[Image: see text] Mononuclear nonheme Fe(II) (MNH) and α-ketoglutarate (α-KG) dependent halogenases activate O(2) to perform oxidative halogenations of activated and nonactivated carbon centers. While the mechanism of halide incorporation into a substrate has been investigated, the mechanism by whic...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4091267/ https://www.ncbi.nlm.nih.gov/pubmed/24847780 http://dx.doi.org/10.1021/ja503179m |