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The Role of Chloride in the Mechanism of O(2) Activation at the Mononuclear Nonheme Fe(II) Center of the Halogenase HctB

[Image: see text] Mononuclear nonheme Fe(II) (MNH) and α-ketoglutarate (α-KG) dependent halogenases activate O(2) to perform oxidative halogenations of activated and nonactivated carbon centers. While the mechanism of halide incorporation into a substrate has been investigated, the mechanism by whic...

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Detalles Bibliográficos
Autores principales:	Pratter, Sarah M., Light, Kenneth M., Solomon, Edward I., Straganz, Grit D.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2014
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4091267/ https://www.ncbi.nlm.nih.gov/pubmed/24847780 http://dx.doi.org/10.1021/ja503179m

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