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n→π* Interactions Engender Chirality in Carbonyl Groups

[Image: see text] An n→π* interaction stems from the delocalization of the electron pair (n) of a donor group into the antibonding orbital (π*) of a carbonyl group. Crystallographic analyses of five pairs of diastereoisomers demonstrate that an n→π* interaction can induce chirality in an otherwise p...

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Detalles Bibliográficos
Autores principales: Choudhary, Amit, Newberry, Robert W., Raines, Ronald T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4096190/
https://www.ncbi.nlm.nih.gov/pubmed/24926562
http://dx.doi.org/10.1021/ol5012967