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n→π* Interactions Engender Chirality in Carbonyl Groups
[Image: see text] An n→π* interaction stems from the delocalization of the electron pair (n) of a donor group into the antibonding orbital (π*) of a carbonyl group. Crystallographic analyses of five pairs of diastereoisomers demonstrate that an n→π* interaction can induce chirality in an otherwise p...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4096190/ https://www.ncbi.nlm.nih.gov/pubmed/24926562 http://dx.doi.org/10.1021/ol5012967 |