Asymmetric Synthesis of α-Branched Amines via Rh(III)-Catalyzed C–H Bond Functionalization

[Image: see text] The first asymmetric intermolecular addition of non-acidic C–H bonds to imines is reported. The use of the activating N-perfluorobutanesulfinyl imine substituent is essential for achieving sufficient reactivity and provides outstanding diastereoselectivity (>98:2 dr). Straightfo...

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Detalles Bibliográficos
Autores principales: Wangweerawong, Apiwat, Bergman, Robert G., Ellman, Jonathan A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4105057/
https://www.ncbi.nlm.nih.gov/pubmed/24901217
http://dx.doi.org/10.1021/ja5033452

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4105057/
https://www.ncbi.nlm.nih.gov/pubmed/24901217
http://dx.doi.org/10.1021/ja5033452

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