Rational Design of a Second Generation Catalyst for Preparation of Allylsilanes Using the Silyl-Heck Reaction

[Image: see text] Using rational ligand design, we have developed of a second-generation ligand, bis(3,5-di-tert-butylphenyl)(tert-butyl)phosphine, for the preparation of allylsilanes using the palladium-catalyzed silyl-Heck reaction. This new ligand provides nearly complete suppression of starting...

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Detalles Bibliográficos
Autores principales: McAtee, Jesse R., Yap, Glenn P. A., Watson, Donald A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4105080/
https://www.ncbi.nlm.nih.gov/pubmed/25003502
http://dx.doi.org/10.1021/ja505446y

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4105080/
https://www.ncbi.nlm.nih.gov/pubmed/25003502
http://dx.doi.org/10.1021/ja505446y

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