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Zinc-Catalyzed Highly Isoselective Ring Opening Polymerization of rac-Lactide
[Image: see text] A family of chiral zinc amido-oxazolinate complexes are shown to be highly active and isoselective initiators for the ring-opening polymerization (ROP) of rac-lactide, yielding isotactic stereoblock polylactides (PLA) with P(m) up to 0.91. This represents the highest isoselectivity...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4105174/ https://www.ncbi.nlm.nih.gov/pubmed/25068079 http://dx.doi.org/10.1021/mz5002959 |