Zinc-Catalyzed Highly Isoselective Ring Opening Polymerization of rac-Lactide

[Image: see text] A family of chiral zinc amido-oxazolinate complexes are shown to be highly active and isoselective initiators for the ring-opening polymerization (ROP) of rac-lactide, yielding isotactic stereoblock polylactides (PLA) with P(m) up to 0.91. This represents the highest isoselectivity...

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Autores principales: Abbina, Srinivas, Du, Guodong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4105174/
https://www.ncbi.nlm.nih.gov/pubmed/25068079
http://dx.doi.org/10.1021/mz5002959
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author Abbina, Srinivas
Du, Guodong
author_facet Abbina, Srinivas
Du, Guodong
author_sort Abbina, Srinivas
collection PubMed
description [Image: see text] A family of chiral zinc amido-oxazolinate complexes are shown to be highly active and isoselective initiators for the ring-opening polymerization (ROP) of rac-lactide, yielding isotactic stereoblock polylactides (PLA) with P(m) up to 0.91. This represents the highest isoselectivity observed with zinc-based catalysts for ROP of rac-lactide.
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spelling pubmed-41051742015-07-02 Zinc-Catalyzed Highly Isoselective Ring Opening Polymerization of rac-Lactide Abbina, Srinivas Du, Guodong ACS Macro Lett [Image: see text] A family of chiral zinc amido-oxazolinate complexes are shown to be highly active and isoselective initiators for the ring-opening polymerization (ROP) of rac-lactide, yielding isotactic stereoblock polylactides (PLA) with P(m) up to 0.91. This represents the highest isoselectivity observed with zinc-based catalysts for ROP of rac-lactide. American Chemical Society 2014-07-02 2014-07-15 /pmc/articles/PMC4105174/ /pubmed/25068079 http://dx.doi.org/10.1021/mz5002959 Text en Copyright © 2014 American Chemical Society Terms of Use (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html)
spellingShingle Abbina, Srinivas
Du, Guodong
Zinc-Catalyzed Highly Isoselective Ring Opening Polymerization of rac-Lactide
title Zinc-Catalyzed Highly Isoselective Ring Opening Polymerization of rac-Lactide
title_full Zinc-Catalyzed Highly Isoselective Ring Opening Polymerization of rac-Lactide
title_fullStr Zinc-Catalyzed Highly Isoselective Ring Opening Polymerization of rac-Lactide
title_full_unstemmed Zinc-Catalyzed Highly Isoselective Ring Opening Polymerization of rac-Lactide
title_short Zinc-Catalyzed Highly Isoselective Ring Opening Polymerization of rac-Lactide
title_sort zinc-catalyzed highly isoselective ring opening polymerization of rac-lactide
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4105174/
https://www.ncbi.nlm.nih.gov/pubmed/25068079
http://dx.doi.org/10.1021/mz5002959
work_keys_str_mv AT abbinasrinivas zinccatalyzedhighlyisoselectiveringopeningpolymerizationofraclactide
AT duguodong zinccatalyzedhighlyisoselectiveringopeningpolymerizationofraclactide

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