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Zinc-Catalyzed Highly Isoselective Ring Opening Polymerization of rac-Lactide

[Image: see text] A family of chiral zinc amido-oxazolinate complexes are shown to be highly active and isoselective initiators for the ring-opening polymerization (ROP) of rac-lactide, yielding isotactic stereoblock polylactides (PLA) with P(m) up to 0.91. This represents the highest isoselectivity...

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Detalles Bibliográficos
Autores principales:	Abbina, Srinivas, Du, Guodong
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2014
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4105174/ https://www.ncbi.nlm.nih.gov/pubmed/25068079 http://dx.doi.org/10.1021/mz5002959

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